[UPSC CSE 2021] Thermodynamics (Q35, 10M)

Calculate the critical constants for \mathrm{CO_2} for which the Van der Waals constants are given by a=0.0072 and b=0.002. Also calculate the Boyle's temperature of \mathrm{CO_2}. The unit of pressure is atmosphere and the unit of volume is that of a gm-mole of the gas at NTP.